99192-55-9

Basic information

• Product Name: Benzoic acid, 4-[(trimethylsilyl)methyl]-, methyl ester
• CAS NO: 99192-55-9
• Molecular Formula: C12H18O2Si
• Molecular Weight: 222.359
• Mol File: 99192-55-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-[(trimethylsilyl)methyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-[(trimethylsilyl)methyl]-, methyl ester(99192-55-9)
• EPA Substance Registry System: Benzoic acid, 4-[(trimethylsilyl)methyl]-, methyl ester(99192-55-9)

Safety Data

• Hazardous Substances Data: 99192-55-9(Hazardous Substances Data)

Upstream product

• 1822-00-0 trimethylsilylmethyllithium 
• 161497-18-3 methyl 4-(methanesulfonyloxy)benzoate 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 76469-88-0 methyl 4-(cyanomethyl)benzoate 
• 75-77-4 chloro-trimethyl-silane 
• 2417-72-3 Methyl 4-(bromomethyl)benzoate 

Relevant articles and documents

Rhodium-catalyzed silylation and intramolecular arylation of nitriles via the silicon-assisted cleavage of carbon-cyano bonds

A rhodium-catalyzed silylation reaction of carbon - cyano bonds using disilane has been developed. Under these catalytic conditions, carbon-cyano bonds in aryl, alkenyl, allyl, and benzyl cyanides bearing a variety of functional groups can be silylated. The observation of an enamine side product in the silylation of benzyl cyanides and related stoichiometric studies indicate that the carbon-cyano bond cleavage proceeds through the deinsertion of silyl isocyanide from η2-iminoacyl complex B. Knowledge gained from these studies has led to the development of a new intramolecular biaryl coupling reaction in which aryl cyanides and aryl chlorides are cross-coupled.

AN ELECTROREDUCTIVE SYNTHESIS OF ALLYLSILANES AND BENZYLSILANES

The electrochemical reduction of benzyl and allyl halides carried out in the presence of chlorotrimethylsilane afforded the corresponding benzylsilanes and allylsilanes in satisfactory yields.