99192-69-5Relevant academic research and scientific papers
Inversion of Configuration at the Phosphorus Nucleophile in the Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides
Muldoon, Jake A.,Varga, Balázs R.,Deegan, Meaghan M.,Chapp, Timothy W.,E?rd?gh, ádám M.,Hughes, Russell P.,Glueck, David S.,Moore, Curtis E.,Rheingold, Arnold L.
, (2018)
Nucleophilic substitution results in inversion of configuration at the electrophilic carbon center (SN2) or racemization (SN1). The stereochemistry of the nucleophile is rarely considered, but phosphines, which have a high barrier to
Phosphinidene transfer reactions of the terminal phosphinidene complex Cp2Zr(PC6H2-2,4,6-t-Bu3)(PMe 3)
Breen, Tricia L.,Stephan, Douglas W.
, p. 11914 - 11921 (2007/10/03)
The terminal zirconium phosphinidene complex Cp2Zr(PR*)(PMe3) (R* = C6H2-2,4,6-t-Bu3) 2 has been synthesized in high yield, and its reactivity has been investigated. The compound Cp2ZrMe(PH
PREPARATION OF STABLE PHOSPHIRANES FROM PHOSPHIDE AND EPOXIDE ASSISTED BY SILICON
Yoshifuji, Masaaki,Toyota, Kozo,Inamoto, Naoki
, p. 441 - 442 (2007/10/02)
Sterically protected E- and Z-1-(2,4,6-tri-t-butylphenyl)-2-phenylphosphiranes were prepared from the corresponding silylphosphide and styrene oxide: the reaction might involve unusual rearrangement and elimination of a silyl group.
