99230-45-2Relevant academic research and scientific papers
Simple preparation of α-diazo esters
Taber, Douglass F.,Sheth, Ritesh B.,Joshi, Pramod V.
, p. 2851 - 2854 (2005)
(Chemical Equation Presented) The TiCl4-mediated reaction of an ester with benzoyl chloride results in high yields of the α-benzoylated ester. Diazo transfer of the benzoylated ester utilizing p- acetoamidobenzenesulfonyl azide affords the α-diazo ester in good yield. Using this simplified procedure, it is easy to prepare gram quantities of α-diazo esters.
