99232-41-4Relevant articles and documents
New Benzylpotassium Reagents and Their Utility for the Synthesis of Homoleptic Uranium(IV) Benzyl Derivatives
Johnson, Sara A.,Kiernicki, John J.,Fanwick, Phillip E.,Bart, Suzanne C.
, p. 2889 - 2895 (2015)
A new family of benzylpotassium reagents, KBn′(1-Bn′) (Bn′ = p-iPrBn, p-tBuBn, p-NMe2Bn, p-SMeBn, m-OMeBn, o-OMeBn, 2-picolyl), was synthesized using a modified literature procedure and characterized by multinuclear NMR sp
QUANTUM CHEMICAL CALCULATIONS AND NUCLEAR MAGNETIC RESONANCE MEASUREMENTS ON BENZYL-TYPE CARBANIONS. PART 1. THE EFFECT OF AN AROMATIC METHOXY SUBSTITUENT (RESONANCE SATURATION) AND α-ALKYL SUBSTITUTION
Vanermen, Guido,Toppet, Suzanne,Van Beylen, Marcel,Geerlings, Paul
, p. 699 - 706 (2007/10/02)
Ab initio STO-3G quantum chemical calculations are reported for benzyl-type carbanions.The influence of aromatic ring substitution by a methoxy group (ortho or para) and of α-alkyl substitution on the electronic properties of the carbanions are investigat
