99236-19-8

Basic information

• Product Name: Ethanone, 1-(4-methoxyphenyl)-2-[(4-methylphenyl)thio]-
• CAS NO: 99236-19-8
• Molecular Formula: C16H16O2S
• Molecular Weight: 272.368
• Mol File: 99236-19-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(4-methoxyphenyl)-2-[(4-methylphenyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-methoxyphenyl)-2-[(4-methylphenyl)thio]-(99236-19-8)
• EPA Substance Registry System: Ethanone, 1-(4-methoxyphenyl)-2-[(4-methylphenyl)thio]-(99236-19-8)

Safety Data

• Hazardous Substances Data: 99236-19-8(Hazardous Substances Data)

Upstream product

• 106-45-6 para-thiocresol 
• 2632-13-5 2-Bromo-4'-methoxyacetophenone 
• 768-60-5 4-methoxyphenylacetylen 
• 34910-42-4 1-(1-azidovinyl)-4-methoxybenzene 
• 121-98-2 methyl 4-methoxybenzoate 
• 100-09-4 4-methoxybenzoic acid 
• 1062682-26-1 1-(4-methoxyphenyl)-3-[4-(trifluoromethyl)phenyl]propane-1,3-dione 
• 103-19-5 di(p-tolyl) disulfide 
• 18362-51-1 1,3-bis(4'-methoxyphenyl)propane-1,3-dione 

Downstream Products

• 1586031-07-3 C₁₈H₂₀O₃S 
• 86516-51-0 1-(4-methoxyphenyl)-2-tosylethanone 
• 103-19-5 di(p-tolyl) disulfide 
• 100-06-1 1-(4-methoxyphenyl)ethanone 

Relevant articles and documents

Electrocatalytic Synthesis of gem -Bisarylthio Enamines and α-Phenylthio Ketones via a Radical Process under Mild Conditions

The novel method for the synthesis of gem -bisarylthio enamines and α-phenylthio ketones was developed via the coupling of α-substituted vinyl azides with thiols in the presence of tetrabutylammonium iodide (TBAI) as a redox catalyst and electrolyte at ro

Effective method of β-keto sulfones synthesis

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Photoreactions of β-Ketosulphides: Aryl and Benzyl Phenacyl Sulphides and Related Compounds

Photoreactions of aryl phenacyl sulphides were studied, particularly in regard to substituent and solvent effects.In general, aryl phenacyl sulphides Ar1SCH2COAr2 1 = p-tolyl, Ar2 = p-X-C6H4 (X = H, Cl, OH, OMe, and Ph), 2-thienyl, and 2-furyl; Ar1 = 2,4,6-trimethylphenyl, Ar2 = Ph and p-HOC6H4; Ar1 = 2-benzthiazolyl, Ar2 = Ph> underwent photochemical cleavage to disulphides (Ar1S)2 and ketones Ar2COMe.In a few cases a diketone (Ar2COCH2)2 was the only, or major, carbonyl photoproduct.Similar photochemical behaviour was shown by ketosulphides p-Me-C6H4SCH(R)COPh (R = PhCH2, PhCOCH2, and p-Me-C6H4S) and related acetophenone derivatives PhCOCH2SR (R = COPh, SO3Na, and SCH2COPh).In a few instances, from p-Me-C6H4SCH2COAr (Ar = Ph, p-Cl-C6H4, and p-Ph-C6H4), a minor photoproduct was a 2-aryl-5-methylbenzothiophen.Benzyl phenacyl sulphides p-X-C6H4COCH2SCH2Ph (X = OH and OMe) also underwent photo-cleavage to give dibenzyl disulphide and a ketone.Free-radical cleavage products ArCOCH2(.) (Ar = Ph and p-MeO-C6H4) and p-Me-C6H4S(.) were trapped as adducts p-Me-C6H4SC(Ph)2CH2CH2COAr when irradiation of the ketosulphide was carried out in the presence of 1,1-diphenylethylene. 2,5-Diphenylfuran was formed photochemically from 1,4-diphenylbutane-1,4-dione on irradiation in methanol.