99266-93-0Relevant academic research and scientific papers
A HIGHLY EFFICIENT SYNTHESIS OF OPTICALLY PURE γ-IODO ALLYLIC ALCOHOLS AND THEIR CONVERSION INTO VARIOUS OPTICALLY ACTIVE ALLYLIC ALCOHOLS
Kitano, Yasunori,Matsumoto, Takashi,Wakasa, Takenori,Okamoto, Sentaro,Shimazaki, Toshiyuki,et al.
, p. 6351 - 6354 (2007/10/02)
Kinetic resolution of γ-iodo allylic alcohols 1 by the Sharpless asymmetric epoxidation reaction proceeds with very large rate differences for the two enantiomers, thus providing a highly efficient method for preparation of optically pure 1.The alcohols 1
3-Substituted iodo alkenyl compounds and methods for preparing same
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, (2008/06/13)
Compounds of the formula: SPC1 Where R is hydrogen, methyl or ethyl; R' is hydrogen, a saturated hydrocarbon chain containing from 1 to about 9 carbon atoms, pentene, hexene, cyclohexyl, or benzyl X is hydrogen, pyranoxy, OR" where R" is a hydrocarbon chain containing from 1 to about 5 carbon atoms or benzyl, EQU1 where R"' is a hydrocarbon chain containing from 1 to about 8 carbon atoms or benzyl, or EQU2 where R1 and R2 are each a hydrocarbon chain containing from 1 to about 5 carbon atoms, and n is an integer from 0 to 5 These compounds are key intermediates in the production of prostaglandins and exhibit antibacterial properties.
