99277-36-8

Upstream product

• 58766-02-2 4-<(tetrahydropyran-2-yl)oxy>butylmagnesium chloride 
• 91796-57-5 4-Methyl-benzenesulfinic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester 

Downstream Products

• 122651-62-1 (R_S)-1-hydroxy-8-(tetrahydropyran-2-yl)oxy-5-(p-tolyl)sulfinyloctan-4-one 
• 99277-37-9 (R_s)-4-<(p-tolyl)sulfinyl>butan-1-ol 
• 122629-86-1 (R_S)-8-acetoxy-1-(tetrahydropyran-2-yl)oxy-4-(p-tolyl)sulfinylnonan-5-one 
• 112996-16-4 (S)-4-[3-((S)-Toluene-4-sulfinyl)-5,6-dihydro-4H-pyran-2-yl]-butan-2-ol 
• 112996-15-3 (R)-4-[3-((S)-Toluene-4-sulfinyl)-5,6-dihydro-4H-pyran-2-yl]-butan-2-ol 
• 112996-14-2 (R_S)-8-hydroxy-1-(tetrahydropyran-2-yl)oxy-4-(p-tolyl)sulfinylnonan-5-one 
• 99277-44-8 (5R,6R)-5-((R)-Toluene-4-sulfinyl)-1,7-dioxa-spiro[5.5]undecane 
• 112996-22-2 4-Oxo-8-(tetrahydro-pyran-2-yloxy)-5-((R)-toluene-4-sulfinyl)-octanoic acid methyl ester 
• 113016-75-4 3-[3-((S)-Toluene-4-sulfinyl)-5,6-dihydro-4H-pyran-2-yl]-propionic acid (S)-toluene-4-sulfinylmethyl ester 
• 122629-87-2 Acetic acid 8-hydroxy-1-methyl-4-oxo-5-((R)-toluene-4-sulfinyl)-octyl ester 
• 122629-88-3 (R_S)-6-(3-acetoxybutyl)-3,4-dihydro-5-(p-tolyl)sulfinyl-2H-pyran 
• 112996-23-3 3-[3-((S)-Toluene-4-sulfinyl)-5,6-dihydro-4H-pyran-2-yl]-propionic acid methyl ester 
• 112996-15-3 4-[3-((S)-Toluene-4-sulfinyl)-5,6-dihydro-4H-pyran-2-yl]-butan-2-ol 
• 122629-84-9 (R_S)-1-acetoxy-8-(tetrahydropyran-2-yl)oxy-5-(p-tolyl)sulfinyloctan-4-one 

Relevant academic research and scientific papers

INTRAMOLECULAR MICHAEL ADDITION REACTION TO CHIRAL VINYLIC SULFOXIDES. AN ENANTIOSELECTIVE SYNTHESIS OF (R)- AND (S)-1,7-DIOXASPIROUNDECANE

(R)- and (S)-1,7-Dioxaspiroundecane , sex pheromone of an olive fly, was each stereoselectively synthesized using an intramolecular Michael addition of hydroxyl group to a chiral vinylic sulfoxide moiety as an asymmetric induction step.