99307-07-0

Basic information

• Product Name: Carbamothioic acid, phenyl-, S-2-propenyl ester
• CAS NO: 99307-07-0
• Molecular Formula: C10H11NOS
• Molecular Weight: 193.269
• Mol File: 99307-07-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Carbamothioic acid, phenyl-, S-2-propenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamothioic acid, phenyl-, S-2-propenyl ester(99307-07-0)
• EPA Substance Registry System: Carbamothioic acid, phenyl-, S-2-propenyl ester(99307-07-0)

Safety Data

• Hazardous Substances Data: 99307-07-0(Hazardous Substances Data)

Upstream product

• 5816-31-9 O-(2-propenoyl) N-phenylmonothiocarbamate 
• 42068-67-7 chlorothioformic acid allyl ester 
• 62-53-3 aniline 
• 870-23-5 prop-2-ene-1-thiol 
• 103-71-9 phenyl isocyanate 
• 21561-99-9 N-methyl-N'-phenyl-N-nitrosourea 

Relevant articles and documents

Bond-Weakening Catalysis: Conjugate Aminations Enabled by the Soft Homolysis of Strong N-H Bonds

The ability of redox-active metal centers to weaken the bonds in associated ligands is well precedented, but has rarely been utilized as a mechanism of substrate activation in catalysis. Here we describe a catalytic bond-weakening protocol for conjugate a

Photochemical Isomerization of O-Allyl and O-But-3-enyl Thiocarbamates

The photochemistry of O-allyl and O-but-3-enyl thiocarbamates has been studied.Photolysis of benzene solutions of O-allyl N-phenylthiocarbamates gave S-allyl N-phenylthiocarbamates.The 1,3-allyl migration from the oxygen to the sulfur involves a concerted process.The same type of 1,3-migration took place in the conversion of O-benzyl N-phenylthiocarbamate into S-benzyl N-phenylthiocarbamate.Irradiation of O-but-3-enylthiocarbamates produced iminooxolanes via aminothietane intermediates.In the case of O-but-3-enyl N-benzoyl-N-phenylthiocarbamates, 3-(benzoylmethyl)-2-phenyliminooxolanes were obtained via a ring opening of the aminothietanes involving a 1,5-benzoyl shift.

N-Nitroso Compounds. IV. Reaction of N-Nitrosourea with Thiol. A New Synthesis of Thiocarbamic S-Esters

Thirteen thiocarbamic S-esters have been prepared in good yield by the reaction of thiol with substituted N-methyl-N-nitrosourea in anhydrous acetonitrile.