99315-90-9Relevant articles and documents
Reaction of 1,3-Dithiane with Nitriles: Generation of Primary Aminoketene Thioacetals
Page, Philip C. Bulman,Niel, Monique B. van,Williams, P. Howard
, p. 742 - 743 (1985)
The anions derived from 1,3-dithiane and 2-trimethylsilyl-1,3-dithiane react with simple nitriles to provide primary aminoketene thioacetals.
REACTIONS OF METALLATED 1,3-DITHIANES WITH CARBOXYLIC ACID DERIVATIVES
Page, Philip C. Bulman,van Niel, Monique B.,Westwood, Donald
, p. 269 - 276 (2007/10/02)
2-Lithio-1,3-dithiane and 2-lithio-2-trimethylsilyl-1,3-dithiane react with nitriles to afford primary aminoketene dithioacetals in good yields; these compounds exhibit marked ambident nucleophilicity.Use of other carboxylic acid derivatives as electrophi