99329-32-5Relevant academic research and scientific papers
Gold(I)-catalyzed Benzylation of (Hetero)aryl Boronic Acids with (Hetero)benzyl Bromides by the Strategy of a SN2-type Reaction
Zang, Wenqing,Wei, Yin,Shi, Min
supporting information, p. 2791 - 2795 (2018/09/20)
Herein, the first example of gold-catalyzed benzylation of (hetero)aryl boronic acids with (hetero)benzyl bromides to give the corresponding cross-coupling products in moderate to good yields is reported. The reaction proceeds through a possible intermolecular SN2-type reaction pathway to give a wide variety of di(hetero)arylmethanes as the desired products. An intriguing reaction mechanism has been proposed on the basis of control experiments, 31P-NMR spectroscopic detection and DFT calculations.
Solvent Effects on Isomer Distributions and Relative Rates in Friedel-Crafts Benzylation and Benzoylation of Dibenzofuran Derivatives
Keumi, Takashi,Nakamura, Masatoshi,Kitamura, Masao,Tomioka, Naoto,Kitajima, Hidehiko
, p. 909 - 914 (2007/10/02)
The positional reactivity order in Friedel-Crafts benzoylation and benzylation of dibenzofuran (DBF) is found to be 2 > 3 > 1 >= 4.Both the partial rate factors and the positional selectivity for the benzylation of DBF are very low compared with those of
