99332-99-7

Upstream product

• 6803-40-3 1-hexylthiocyanate 
• 142-61-0 Hexanoyl chloride 
• 111-31-9 Hexanethiol 
• 1119-67-1 1-iodo-1-hexyne 

Relevant academic research and scientific papers

Reductive cleavage of C - S bond by samarium diiodide: A novel method for the synthesis of disulfides and thiolesters

Disulfides were obtained by the reaction of thiocyanates with equivalent SmI2. Smarium thiolates were generated by the reaction of an equivalent of thiocyanates with two equivalents of SmI2, and then reacted smoothly with acyl chlorides to give thiolesters.

Synthesis of S-Alkyl Alkanethioates via 1-Iodoalk-1-enyldialkylboranes

S-Alkyl alkanethioates were formed in high yields by successive reactions of 1-iodoalk-1-enyl-bis(1,2-dimethylpropyl)boranes with alkylthiomagnesium bromides and alkaline hydrogen peroxide.