99340-08-6Relevant academic research and scientific papers
Synthesis and Properties of Chiral Macrobicyclic and Macrotricyclic Cryptands Containing the trans-Tetrahydrofuran-2,5-diylbis(methylene) Subunit as the Chiral Center
Naemura, Koichiro,Kanda, Yuji,Iwasaka, Hiroshi,Chikamatsu, Hiroaki
, p. 1789 - 1792 (1987)
The macrobicyclic and macrotricyclic cryptands containing the trans-tetrahydrofuran-2,5-diylbis(methylene) molecular framework as the chiral subunit were prepared in optically active forms.The enantiomer recognition property of the macrotricyclic tetracarboxamide (+)-6 in transport of enantiomeric molecules was examined, and the cation-binding abilities of the macrotricyclic and macrobicyclic amines 7, 10, and 13 were also investigated.
SYNTHESIS OF (+)-(3S,6S,10S,13S,17S,20S,24S,27S)-1,8,15,22-TETRAZA-3,6;10,13;17,20;24,27-TETRAEPOXYCYCLOOCTACOSANE. AN ENANTIOMERICALLY PURE TETRAAZACROWN ETHER WITH D4 SYMMETRY AND OF KNOWN ABSOLUTE CONFIGURATION.
Naemura, Koichiro,Hokura, Yukio,Kanda, Yuji,Nakazaki, Masao
, p. 615 - 616 (2007/10/02)
The title azacrown ether, which was synthesized using (+)-(2S,5S)-trans-2,5-bis(aminomethyl)tetrahydrofuran and (+)-(2S,5S)-trans-2,5-bis(hydroxymethyl)tetrahydrofuran as the C2 building blocks, is the first optically active organic molecule of D4 symmetry with known absolute configuration.
