99356-15-7

Basic information

• Product Name: Silane, trimethyl(2-phenyl-2-butenyl)-, (E)-
• CAS NO: 99356-15-7
• Molecular Formula: C13H20Si
• Molecular Weight: 204.387
• Mol File: 99356-15-7.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl(2-phenyl-2-butenyl)-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl(2-phenyl-2-butenyl)-, (E)-(99356-15-7)
• EPA Substance Registry System: Silane, trimethyl(2-phenyl-2-butenyl)-, (E)-(99356-15-7)

Safety Data

• Hazardous Substances Data: 99356-15-7(Hazardous Substances Data)

Upstream product

• 93-55-0 1-phenyl-propan-1-one 
• 13170-43-9 (trimethylsilyl)methylmagnesium chloride 
• 39854-50-7 2-ethyl-2-phenyl-1,3-dithiane 
• 6008-82-8 2-ethyl-2-phenyl-1,3-dithiolane 
• 1822-00-0 trimethylsilylmethyllithium 
• 66323-99-7 trimethyl[(Z)-(1-phenyl-1-propenyl)oxy]silane 
• 10409-50-4 phosphoric acid diethyl ester 1-phenyl-propenyl ester 
• 32780-79-3 (Z)-(1-iodoprop-1-en-1-yl)benzene 
• 57482-85-6 <α-(trimethylsilyl)benzyl>magnesium bromide 

Downstream Products

• 1380233-06-6 5-(4,4,4-trifluorobut-1-en-2-yl)benzo[d][1,3]dioxole 

Relevant articles and documents

Silver-promoted cross-coupling of substituted allyl(trimethyl)silanes with aryl iodides by palladium catalysis

A ligand-free Pd-catalyzed cross-coupling of substituted allyl(trimethyl)silanes with aryl iodides enabled by silver salts was developed. This reaction delivered allylic arenes chemoselectively and regioselectively. The study suggested that the reaction might proceed through oxidative addition of ArI to Pd(0) followed by halide abstraction to give an electrophilic complex ArPdX, which further reacted with allyl(trimethyl)silanes via electrophilic addition/desilylation/reductive elimination to afford the allyl-aryl coupling products.

Trifluoromethylation of allylsilanes under copper catalysis

Branched allylic CF3 products are accessible by copper-catalyzed trifluoromethylation of allylsilanes with the Togni reagent I. The silyl group is critical to control the outcome of this reaction because in its absence, a product of addition be

The Effect of the Ring Size of the Dithiolato Leaving Group on the Orientation of β-Elimination in the Nickel-catalysed Alkenation of Cyclic Dithioacetals with Me3SiCH2MgCl

The product distribution (allyl- vs. vinyl-silanes) of the reactions of dithioacetals derived from alkyl aryl ketones with Me3SiCH2MgCl surprisingly depends on ring size of the cyclic dithioacetals, the five-membered ring substrates affording allylsilane as the major product while the six-membered analogues yield vinylsilanes predominantly.These results indicate that the leaving group, dithiolato moiety, may remain coordinated to the metal centre during the course of the catalytic process.