99359-26-9

Basic information

• Product Name: N-allyl-4-bromo-N-methylaniline
• Synonyms: N-allyl-4-bromo-N-methylaniline
• CAS NO: 99359-26-9
• Molecular Weight: 226.116
• Mol File: 99359-26-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-allyl-4-bromo-N-methylaniline(CAS DataBase Reference)
• NIST Chemistry Reference: N-allyl-4-bromo-N-methylaniline(99359-26-9)
• EPA Substance Registry System: N-allyl-4-bromo-N-methylaniline(99359-26-9)

Safety Data

• Hazardous Substances Data: 99359-26-9(Hazardous Substances Data)

Upstream product

• 6628-07-5 N-allyl-N-methylaniline 
• 106-95-6 allyl bromide 
• 100-61-8 N-methylaniline 
• 106-40-1 4-bromo-aniline 
• 947515-73-3 (4-bromophenyl)[2-(hydroxymethyl)phenyl]dimethylsilane 
• 1286764-15-5 N-allyl-N-methyl-O-benzoyl hydroxylamine 
• 6911-87-1 4-bromo-N-methylaniline 

Relevant articles and documents

DMSO-allyl bromide: A mild and efficient reagent for atom economic one-pot: N -allylation and bromination of 2°-aryl amines, 2-aryl aminoamides, indoles and 7-aza indoles

A mixture DMSO-allyl bromide has been developed as a reagent for an atom economic one-pot N-allylation and aryl bromination under basic conditions. Utilizing this reagent, N-allylation-bromination of a number of 2°-aryl amines, aryl aminoamides, indoles, and 7-aza indoles has been achieved. The scope of the substrates and limitations, the synthetic utility of the products, and a plausible reaction mechanism have been proposed.

Copper-catalyzed electrophilic amination of arylsilanes with hydroxylamines

A copper-catalyzed electrophilic amination of aryl[(2-hydroxymethyl)phenyl] dimethylsilanes with O-acylated hydroxylamines has been developed to afford the corresponding anilines in good yields. The catalytic reaction proceeds very smoothly under mild conditions and tolerates a wide range of functional groups.