99367-29-0Relevant academic research and scientific papers
Conformational supramolecular isomerism in one-dimensional silver(i) coordination polymer of a flexible bis(bidentate) N,N-donor ligand with p-xylyl spacer
Chakraborty, Biswarup,Halder, Partha,Paine, Tapan Kanti
, p. 3647 - 3654 (2011)
The isolation and structural characterisation of three isomeric silver(i) complexes, 1a, 1b and 2 with the general formula {[AgL1]ClO 4}n (where L1 is a bis(bidentate) N,N-donor ligand derived from the Schiff-ba
CuII complexes of isomeric ligands derived from 2-pyridine-carboxaldehyde and m- or p-xylylenediamine: An intermolecularly- stacked dinuclear species and a trinuclear circular helicate that encapsulates a chloride ion
Lee, Young Hoon,Woo, Arim,Won, Mi Seon,Cho, Jeong Hwan,Clegg, Jack K.,Hayami, Shinya,Thuery, Pierre,Lindoy, Leonard F.,Kim, Yang
, p. 1587 - 1593 (2012)
Di- and trinuclear CuII complexes [Cu2L 1(2,2′-bipyridine)2Cl2]Cl 2·11H2O and [Cu3(L2) 3Cl3]Cl3·1.25MeOH·4H 2O i
The influence of α,α′-diimine bridging ligand on the reactivity of binuclear para-cymene ruthenium(II) complexes. Kinetic, mechanistic and computational study
Jaganyi, Deogratius,Mambanda, Allen,Mutua, Gershom Kyalo,Onunga, Daniel O.,Sitati, Meshack
, (2020/09/15)
Substitution kinetics of the aqua ligands in four binuclear ruthenium(II) para-cymene complexes with different α,α′-diimine bridging ligands [2-pyridylaldazine (Ru-1), p-phenylenebis(picoline)aldimine (Ru-2), p-biphenylenebis(picoline)aldimine (Ru-3) and
Steric and electronic effects in the formation and carbon disulfide reactivity of dinuclear nickel complexes supported by bis(iminopyridine) ligands
Bheemaraju, Amarnath,Beattie, Jeffrey W.,Tabasan, Erwyn G.,Martin, Philip D.,Lord, Richard L.,Groysman, Stanislav
, p. 2952 - 2962 (2013/06/27)
We are developing bimetallic platforms for the cooperative activation of heteroallenes. Toward this goal, we designed a new family of bis(iminopyridine) ((N,N′-1,1′-(1,4-phenylene)bis(N-(pyridin-2-ylmethylene)methanamine) and N,N′-1,1′-(1,4-phenylene)bis(N-(1-(pyridin-2-yl)ethylidene) methanamine)) dinickel complexes, synthesized their CS2 compounds, and studied their reactivity. Bis(iminopyridine) ligands L react with Ni(COD)2 to form Ni2(L)2 complexes or Ni 2(L)(COD)2 complexes as a function of the steric and electronic properties of the ligand precursor. Product structures disclosed an anti geometry in the Ni2(L)(COD)2 species and helical (anti) structures for Ni2(L)2 complexes. Carbon disulfide adducts Ni2(L)(CS2)2 were obtained in good yields upon addition of CS2 to Ni2(L)(COD)2 or in a one-pot reaction of L with 2 equiv of both Ni(COD)2 and CS 2. Ni2(L)(CS2)2 complexes are highly flexible, displaying both syn and anti conformations (shortest S- - -S separations of 5.0 and 9.5 A, respectively) in the solid state. DFT calculations demonstrate virtually no energy difference between the two conformations. Electrochemical studies of the Ni2(L)(CS 2)2 complexes displayed two ligand-based reductions and a broad CS2-based oxidation. Chemical oxidation with [FeCp 2]+ liberated free CS2. The addition of NHC (NHC = 1,3-di-tert-butylimidazolin-2-ylidene) to Ni2(L)(CS 2)2 yielded Ni2(NHC)2(CS 2)2, in which both carbon disulfide ligands are bridging two Ni centers.
A new class of solvatochromic material: Geometrically unsaturated Ni (II) complexes
Selvakumar, P. Mosae,Nadella, S.,Subramanian, P. S.,Froehlich, R.,Albrecht, M.
, p. 563 - 571,9 (2020/07/31)
A series of Ni(II) double stranded binuclear complexes were synthesized upon treating the Ni(II) salts with series of diamino-bis-pyridine ligands, L1H2-L4H2 in 1:1 stiochiometric ratio. The Ni(II) centers exist
