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General Acid Catalysis in the Hydrolysis of 1,3-Dioxolanes and 1,3-Oxathiolanes. The Hydrolysis of Acetals and Thioacetals of p-(Dimethylamino)benzaldehyde
Fife, Thomas H.,Natarajan, R.
, p. 2425 - 2430 (2007/10/02)
Rate constants have been determined for hydrolysis of acetal and O,S-thioacetal derivatives of p-(dimethylamino)benzaldehyde in H2O.The plots of log kobsd vs. pH for the di-n-propyl acetal, the 1,3-dioxolane, and the 1,3-oxathiolane are pH inde
