99384-48-2Relevant academic research and scientific papers
Pyrothiocarbonates; IV. Synthesis of Potassium O-Alkyl Thiocarbonates and Their Use in the Preparation of Symmetrical and Unsymmetrical Dialkoxycarbonyl Sulfides
Palominos, Mario A.,Vega, Juan C.
, p. 825 - 826 (2007/10/02)
Alkyl group interchange (transesterification) proceeds on heating a potassium O-alkyl thiocarbonate with an alcohol having an alkyl group different from that of the potassium salt.This transesterification is utilized to prepare potassium O-alkyl thiocarbonates since the direct method by reaction of alkoxide ion with carbonyl sulfide is less efficient.The reaction of potassium O-alkyl thiocarbonates with alkyl carbonochloridates gives symmetrical or unsymmetrical dialkoxycarbonyl sulfides in high yields.
Synthesis and Structure Determination of N-(Alkoxycarbonylsulfenyl)-s-triazine Herbicides
Pilgram, K. H.,Gale, Laird H.
, p. 193 - 200 (2007/10/02)
Various 2-substituted-4,6-bis(alkylamino)-1,3,5-triazines, 1, have been found to react with alkoxycarbonylsulfenyl chlorides, 2, to give the title compounds 3.The structural characterization of 3a in the solid state by single X-ray crystallographic analysis established that it is the isomer wherein the methoxycarbonylthio group is attached to the less sterically hindered, exocyclic nitrogen bearing the ethyl group.
