99420-47-0Relevant academic research and scientific papers
A convenient and stable synthon for ethyl azide and its evaluation in a [3 + 2]-cycloaddition reaction under continuous-flow conditions
Tinder, Rob,Farr, Roger,Heid, Richard,Zhao, Ralph,Rarig Jr., Randy S.,Storz, Thomas
experimental part, p. 1401 - 1406 (2010/04/22)
Azidoethyl phenyl sulfide, a readily accessible and reasonably stable synthon for ethyl azide with acceptable thermal safety properties, was investigated in a preliminary design space evaluation of a [3 + 2]-cycloaddition with cyanoacetamide under continu
HETEROCYCLIZATION OF COMPOUNDS CONTAINING DIAZO AND CYANO GROUPS. TWO PATHWAYS IN THE CYCLIZATION OF 2-DIAZO-2-CYANOACETIC ACID DERIVATIVES UNDER THE INFLUENCE OF BASES
Shafran, Yu. M.,Bakulev, V. A.,Mokrushin, V. S.,Alekseev, S. G.,Lebedev, A. T.,Sharbatyan, P. A.
, p. 740 - 745 (2007/10/02)
1,2,3-Triazol-5-olates are formed in the reaction of diazomalonodiamide and 2-diazo-2-cyanoacetic acid amide and N-methylamide with sodium ethoxide, triethylamine, and ammonia.The products of the reaction of 2-diazo-2-cyanoacetamide with primary amines are mixtures of 4-cyano-1,2,3-triazol-5-olates and 5-amino-1-alkyl-1,2,3-triazole-4-carboxamides.
