99440-90-1

Upstream product

• 1142-20-7 N-Cbz-Ala 
• 88549-93-3 (+/-)-actinobolyl amine hydrofluoride salt 
• 99457-40-6 2-oxabicyclo<3.3.1>non-6-ene-3,4-dione 
• 126423-69-6 N-{(S)-1-[(3aS,4S,6S,7aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-2-hydroxy-propyl}-C-p-tolyl-methanesulfonamide 
• 126423-69-6 N-{(1S,2S)-1-[(3aS,4S,6S,7aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-2-hydroxy-propyl}-C-p-tolyl-methanesulfonamide 
• 99457-40-6 (1S,5S)-2-Oxa-bicyclo[3.3.1]non-6-ene-3,4-dione 
• 126423-66-3 (R)-2-[(3aR,4R,6R,7aR)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-N-methoxy-N-methyl-2-p-tolylmethanesulfonylamino-acetamide 
• 126423-70-9 Acetic acid (1S,2S)-2-[(3aS,4S,6S,7aS)-6-(tert-butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-1-methyl-2-p-tolylmethanesulfonylamino-ethyl ester 
• 126423-65-2 (S)-2-((3aS,4S,6S,7aS)-6-Hydroxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl)-N-methoxy-N-methyl-2-p-tolylmethanesulfonylamino-acetamide 
• 126423-72-1 Acetic acid (1S,2S)-2-((3aS,4S,7aS)-2,2-dimethyl-6-oxo-hexahydro-benzo[1,3]dioxol-4-yl)-1-methyl-2-p-tolylmethanesulfonylamino-ethyl ester 
• 126423-68-5 N-{(S)-1-[(3aS,4S,6S,7aS)-6-(tert-Butyl-dimethyl-silanyloxy)-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl]-2-oxo-ethyl}-C-p-tolyl-methanesulfonamide 
• 126423-74-3 N-((3aS,8S,9S,9aS,9bS)-5-Hydroxy-2,2,8-trimethyl-6-oxo-4,6,8,9,9a,9b-hexahydro-3aH-[1,3]dioxolo[4,5-f]isochromen-9-yl)-C-p-tolyl-methanesulfonamide 
• 126423-71-0 Acetic acid (1S,2S)-2-((3aS,4S,6S,7aS)-6-hydroxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxol-4-yl)-1-methyl-2-p-tolylmethanesulfonylamino-ethyl ester 
• 126423-64-1 (S)-N-Methoxy-N-methyl-2-p-tolylmethanesulfonylamino-2-((1S,2S,3S,5S)-2,3,5-trihydroxy-cyclohexyl)-acetamide 

Relevant academic research and scientific papers

Stereoselective total syntheses of the antitumor antibiotics (+)-actinobolin and (-)-bactobolin from a common bridged lactone intermediate

Efficient, highly steroselective approaches have been developed to (+)-actinobolin (1) and (-)-bactobolin (3) from bridged α-keto lactone 11, which can be readily prepared via intramolecular SnCl4 catalyzed ene reaction of cyclohexenol glyoxyla