99583-46-7Relevant academic research and scientific papers
A novel and convenient synthesis of 2-aryl-4-methylenetetrahydrofurans from 2-(trimethylsiloxymethyl)allyltrimethylsilane and acetals
Oriyama,Ishiwata,Sano,Matsuda,Takahashi,Koga
, p. 5581 - 5584 (1995)
The reaction of acetals with 2-(trimethylsiloxymethyl)allyltrimethylsilane under the influence of the combined use of a catalytic amount of tin(II) halide and acetyl halide affords the corresponding 2-aryl-4-methylenetetrahydrofurans in good yields.
Palladium-Catalyzed Trimethylenemethane Reaction To Form Methylenetetrahydrofurans. Aldehyde and Ketone Substrates and the Tin Effect
Trost, Barry M.,King, Steven A.,Schmidt, Thomas
, p. 5902 - 5915 (2007/10/02)
The palladium-catalyzed trimethylenemethane (TMM) cycloaddition of carbonyl compounds has been shown to have a strong dependence upon the presence of cocatalysts such as tri-n-butyltin acetate, di-n-butyltin diacetate, or trimethyltin acetate.High-yieldin
A Two Catalyst System For Cycloaddition of a Trimethylenemethane Fragment to Aldehydes
Trost, Barry M.,King, Steven A.
, p. 5971 - 5974 (2007/10/02)
The cycloaddition of 2-trimethylsilylmethylallyl acetate to aldehydes is co-catalyzed by a Pd(0) complex and a trialkyltin acetate.
