996-06-5Relevant academic research and scientific papers
Cleavage of Si-C and Ge-C bonds in heterylsilanes and -germanes by organolithium reagents
Gevorgyan, Vladimir,Borisova, Larisa,Lukevics, Edmunds
, p. 381 - 387 (2007/10/02)
Organolithium reagents RLi can cleave Si-C and Ge-C bonds in heterylsilanes and -germanes substituting furyl, dihydrofuryl and dihydropyranyl groups for the organolithium residue R.
Method for the preparation of a tert-hydrocarbyl silyl compound
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, (2008/06/13)
A tert-hydrocarbyl, e.g. tert-butyl, silyl compound can be synthesized easily according to the method of the invention in which a tert-hydrocarbylmagnesium halide as a Grignard reagent is reacted with a silane compound having at least one silicon-bonded hydrogen atom and at least one silicon-bonded halogen atom simultaneously in a molecule in a suitable organic solvent so that the halogen atom in the latter reactant is replaced with the tert-hydrocarbyl group in the former reactant to give the desired tert-hydrocarbyl silyl compound in a high yield without the safety problem in the conventional method using a tert-alkyl lithium as the reactant.
