99604-21-4

Upstream product

• 96302-81-7 (2RS,5SR; E)-5-diphenylphosphinoyldec-3-en-2-ol 
• 96302-64-6 (4RS,5SR;E)-5-diphenylphosphinoyldec-2-en-4-ol 
• 19259-70-2 n-hexyldiphenylphosphine oxide 
• 96302-81-7 (2RS,5RS; E)-5-diphenylphosphinoyldec-3-en-2-ol 

Downstream Products

• 101681-02-1 (2RS,3SR,4SR,5SR)-5-diphenylphosphinoyl-4-(3-phenylpropylsulfanyl)decane-2,3-diol 
• 101681-03-2 (2S,3S,4R,5R)-5-(Diphenyl-phosphinoyl)-3-(3-phenyl-propylsulfanyl)-decane-2,4-diol 
• 101681-03-2 5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol 
• 101681-03-2 (2S,3R,4R,5R)-5-(Diphenyl-phosphinoyl)-3-(3-phenyl-propylsulfanyl)-decane-2,4-diol 
• 101681-04-3 (2RS,3RS,Z)-3-(3-phenylpropylsulfanyl)dec-4-en-2-ol 
• 101681-06-5 1-{(2S,3S)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanone 
• 101681-03-2 (2RS,3SR,4SR,5SR)-5-diphenylphosphinoyl-3-(3-phenylpropylsulfanyl)decane-2,4-diol 
• 101681-04-3 (2RS,3RS,E)-3-(3-phenylpropylsulfanyl)dec-4-en-2-ol 
• 101681-06-5 1-{(2R,3R)-3-[(R)-1-(Diphenyl-phosphinoyl)-hexyl]-oxiranyl}-ethanone 

Relevant academic research and scientific papers

STEREOCONTROLLED (E, Z AND ERYTHRO, THREO) SYNTHESIS OF β-HYDROXYALLYLIC SULPHIDES

All four isomers of substituted 3-alkylthio-4-hydroxybutenes have been synthesised: both the geometry of the double bond and the relative stereochemistry of the two chiral centres are controlled.

STEREOSELECTIVE PERACID EPOXIDATION OF ALLYLIC AND δ-HYDROXYALLYLIC DIPHENYLPHOPHINE OXIDES

The title compounds were epoxidised by m-chloroperbenzoic acid with high stereoselectivity induced by the Ph2PO or hydroxyl groups.