99639-35-7

Basic information

• Product Name: NO₂C₆H₄COPdI(P(C₆H₅)3)2
• Synonyms: NO₂C₆H₄COPdI(P(C₆H₅)3)2
• CAS NO: 99639-35-7
• Molecular Weight: 908.02
• Mol File: 99639-35-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: NO₂C₆H₄COPdI(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: NO₂C₆H₄COPdI(P(C₆H₅)3)2(99639-35-7)
• EPA Substance Registry System: NO₂C₆H₄COPdI(P(C₆H₅)3)2(99639-35-7)

Safety Data

• Hazardous Substances Data: 99639-35-7(Hazardous Substances Data)

Upstream product

• 33377-47-8 (4-nitrophenyl)Pd(P(C₆H₅)3)2I 

Downstream Products

• 619-50-1 4-nitrobenzoic acid methyl ester 
• 3128-43-6 S-phenyl 4-nitrobenzothioate 

Relevant articles and documents

PALLADIUM-CATALYZED SYNTHESIS OF AROMATIC ACID DERIVATIVES BY CARBONYLATION OF ARYL IODIDES AND Alk3SnNu (Nu = MeO, Et2N, PhS, EtS)

Carbonylation of the ArI/Alk3SnNu system (Nu = MeO, Et2N), leading to esters and amides of substituted benzoic acids, occurs readily in the presence of phosphinepalladium complexes.When Nu = PhS and EtS either a cross-coupling product (Ar = p-NO2C6H4) or a carbonylation product (Ar = Ph) is formed predominantly, depending on the nature of ArI.Stoichiometric reactions of ArPdI(PPh3)2 with carbon monoxide, resulting in acylpalladium complexes, and reactions of ArCOPdI(PPh3)2 with Alk3SnNu have been studied.Some mechanistic aspects are discussed.