99648-30-3

Upstream product

• 119930-95-9 6,6,13,13-tetramethyl-1,4,8,11-tetrathiocyclotetradecane 
• 99640-04-7 [Rh((CH₃)4C₁₀H₁₆S₄)]⁽¹⁺⁾*Cl^(1-) = [Rh((CH₃)4C₁₀H₁₆S₄)]Cl 
• 143-66-8 sodium tetraphenyl borate 

Downstream Products

• 99640-08-1 [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]B(C₆H₅)4 

Relevant academic research and scientific papers

Cationic Rhodium(I) Complexes of 1,4,8,11-Tetrathiacyclotetradecane (aneS4) and the 6,6,13,13-Tetramethyl Analogue (Me4aneS4). Preparation of Two Conformers, X-Ray Crystal Structure of (RhaneS4))2Cl2*MeCN, and Conformational Effect on the Nucleophilicity of the Rhodium(I) Ion

Two conformers for the cationic rhodium(I) complexes of the title 14-membered cyclic tetrasulphides have been prepared on the conformational effect upon the nucleophilicity of rhodium(I) ion is shown by the oxidative addition reaction of CH2Cl2; (RhaneS4)Cl (1), in which the Rh atom lies 0.133(2) Angstroem above the plane of four S atoms, forms a dimer through a Rh...Rh and four Rh...S intermolecular non-bonded interactions as established by an X-ray crystal structure determination.