99640-08-1

Basic information

• Product Name: [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]B(C₆H₅)4
• CAS NO: 99640-08-1
• Molecular Weight: 831.713
• Mol File: 99640-08-1.mol

Chemical Properties

• CAS DataBase Reference: [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]B(C₆H₅)4(CAS DataBase Reference)
• NIST Chemistry Reference: [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]B(C₆H₅)4(99640-08-1)
• EPA Substance Registry System: [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [RhCl(CH₂Cl)(CH₃)4(C₁₀H₁₆S₄)]B(C₆H₅)4(99640-08-1)

Safety Data

• Hazardous Substances Data: 99640-08-1(Hazardous Substances Data)

Upstream product

• 99648-30-3 [Rh((CH₃)4C₁₀H₁₆S₄)]⁽¹⁺⁾*B(C₆H₅)4^(1-) = [Rh((CH₃)4C₁₀H₁₆S₄)]B(C₆H₅)4 

Relevant articles and documents

Cationic Rhodium(I) Complexes of 1,4,8,11-Tetrathiacyclotetradecane (aneS4) and the 6,6,13,13-Tetramethyl Analogue (Me4aneS4). Preparation of Two Conformers, X-Ray Crystal Structure of (RhaneS4))2Cl2*MeCN, and Conformational Effect on the Nucleophilicity of the Rhodium(I) Ion

Two conformers for the cationic rhodium(I) complexes of the title 14-membered cyclic tetrasulphides have been prepared on the conformational effect upon the nucleophilicity of rhodium(I) ion is shown by the oxidative addition reaction of CH2Cl2; (RhaneS4)Cl (1), in which the Rh atom lies 0.133(2) Angstroem above the plane of four S atoms, forms a dimer through a Rh...Rh and four Rh...S intermolecular non-bonded interactions as established by an X-ray crystal structure determination.