99648-47-2Relevant articles and documents
Bis(trifluoromethyl)sulfine, (CF3)2C=SO: Addition Reactions with Amines, Alcohols, Hydrogen Halides, and Dienes
Schwab, Michael,Sundermeyer, Wolfgang
, p. 2458 - 2465 (2007/10/02)
Contrary to other sulfines, bis(trifluoromethyl)sulfine (bis(trifluoromethyl)methylene sulfoxide, 7) reacts with amines, alcohols, and hydrogen chloride yielding derivatives of the corresponding sulfinic acid (1-3; 4-6, 8, 9; 10).By the reaction with hydrogen bromide the C-brominated sulfenyl bromide 11 and sulfinyl bromide 14 are formed via a redox reaction. 7 reacts with 2,3-dimethylbutadiene and cyclopentadiene to give the corresponding cyclic adducts 16 and 18, respectively, which with m-chloroperbenzoic acid could be oxidized to the cyclic sulfones 17 and 19.