87108-79-0

Basic information

• Product Name: sulfoxid
• Synonyms: sulfoxid
• CAS NO: 87108-79-0
• Molecular Weight: 198.089
• Mol File: 87108-79-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: sulfoxid(CAS DataBase Reference)
• NIST Chemistry Reference: sulfoxid(87108-79-0)
• EPA Substance Registry System: sulfoxid(87108-79-0)

Safety Data

• Hazardous Substances Data: 87108-79-0(Hazardous Substances Data)

Upstream product

• 107729-33-9 3-<<2,2,2-Trifluor-1-(trifluormethyl)ethyl>sulfinyl>-1-propen 
• 99648-42-7 2-Chlor-1,1,1,3,3,3-hexafluoropropan-2-sulfinylchlorid 
• 1490-33-1 hexafluorothioacetone 

Downstream Products

• 684-16-2 Hexafluoroacetone 
• 791-50-4 2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane 
• 360-57-6 1,1,1,4,4,4-hexafluoro-2,3-bis-trifluoromethyl-but-2-ene 
• 109746-36-3 Benzyl(2,2,2-trifluor-1-trifluormethylethyl)disulfan 
• 102150-18-5 1,1,1,3,3,3-Hexafluor-2-propansulfinsaeureanilid 
• 690-39-1 1,1,1,3,3,3-hexafluoropropane 
• 99648-47-2 1,1,1,3,3,3-Hexafluor-2-propansulfinsaeure 
• 99648-42-7 2-Chlor-1,1,1,3,3,3-hexafluoropropan-2-sulfinylchlorid 
• 109746-40-9 2-Methyl-2-(4-nitro-phenyl)-5,5-bis-trifluoromethyl-2,5-dihydro-[1,3,4]thiadiazole 1-oxide 
• 109746-37-4 5-Phenyl-2,2-bis-trifluoromethyl-2,3-dihydro-[1,3,4]thiadiazole 1-oxide 
• 109746-39-6 2,5-Dihydro-2,2-diphenyl-5,5-bis(trifluormethyl)-1,3,4-thiadiazol-1-oxid 
• 109746-41-0 3-Phenyl-4,4-bis(trifluormethyl)-1,5,2-oxathiazol-5-oxid 

Relevant articles and documents

Methyl-halogenated Allyl Methyl Sulfoxides and Sulfones and the Synthesis of Halogenated Sulfines

Allyl methyl sulfoxides R1R2R3C-S(O)-CH2CH=CH2 1a-7a (R1, R2, R3 = H, F, Cl, CF3) as well as the corresponding sulfones 1b-7b were synthesized.The sulfoxides substituted at the methyl group are in equilibrium with the allyl sulfenates R1R2R3-S-OCH2CH=CH2 depending on temperature and kind of substitution.By pyrolysis of the sulfoxides 2a, 3a, 4a, and 7a the sulfines Cl2C=SO and (CF3)2C=SO could be prepared, and evidence for the existence of the sulfines ClFC=SO and F2C=SO could be obtained.The new pentenes 12 and 14 are described.

Synthesis and Properties of Tetrakis(trifluoromethyl)-1,3-dithietane S-Oxides and Bis(trifluoromethyl)sulfine

The corresponding S-oxides 2-6 could be obtained by oxidation of 2,2,4,4-tetrakis(trifluoromethyl)-1,3-dithietane (1).Similar oxidation of 2,2,4,4-tetrakis(trifluoromethyl)thiirane (8) yields the episulfoxide 12, but not the episulfone 14.Pyrolysis of 2, 3, 5, and 6 have been investigated and bis(trifluoromethyl)sulfine (7) could be isolated as the first member of perfluoroalkylsulfines as well as the sulfonylfluoride 13 being the product of isomerization of bis(trifluoromethyl)sulfene (9). 7 could also be obtained by ring opening from 3 with bases and by oxidation of hexafluorothioacetone (11), respectively.Solvolytic ring opening in 5 and 6 yields the sulfones 16 and 17.