99679-92-2

Upstream product

• 99265-94-8 (2R,4aR,6S,7R,8R,8aR)-8-hydroxy-6-methoxy-2-phenyl-7-phenylcarbonyloxyperhydropyrano[3,2-d][1,3]dioxine 
• 99745-46-7 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-glucopyranosid 
• 99745-49-0 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-allopyranosid 
• 88425-05-2 Methyl-3-azido-2-O-benzoyl-4,6-O-benzyliden-3-desoxy-α-D-glucopyranosid 
• 99745-47-8 methyl 3-azido-3-deoxy-4,6-O-(phenylmethylene)-2-benzoate-α-D-allopyranoside 
• 99679-79-5 methyl 4,6-O-(phenylmethylene)-2-benzoate-3-(trifluoromethanesulfonate)-α-D-glucopyranoside 
• 99679-77-3 Methyl-2-O-benzoyl-4,6-O-benzyliden-3-O-trifluormethylsulfonyl-α-D-allopyranosid 
• 28642-64-0 methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside 
• 501-53-1 benzyl chloroformate 
• 99745-48-9 Methyl-3-amino-4,6-O-benzyliden-3-desoxy-α-D-allopyranosid 
• 99745-99-0 methyl 3-amino-4,6-O-benzylidene-3-deoxy-α-D-glucopyranoside 
• 99679-80-8 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-ribo-hexopyranosid-2-ulose 
• 74-88-4 methyl iodide 
• 99679-78-4 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-arabino-hexopyranosid-2-ulose 

Relevant academic research and scientific papers

Enolates of Carbohydrates, 4. - Axial C-Alkylation in α-Position of α-Amino-α-deoxy-ketoses

Products of type 2a-c, 6, 10a, b, and 14a, b which are alkylated in α-position of the keto function are yielded by reaction of the α-amino-α-deoxy-uloses 1a-c, 5, 9a, and 13a, b with LDA, CH3I, HMPA in THF (method A) or KOtBu, CH3I in DMF (method B) in a