99745-48-9

Upstream product

• 99679-79-5 methyl 4,6-O-(phenylmethylene)-2-benzoate-3-(trifluoromethanesulfonate)-α-D-glucopyranoside 
• 28642-64-0 methyl 2-O-benzoyl-4,6-di-O-benzylidene-α-D-glucopyranoside 
• 99745-47-8 methyl 3-azido-3-deoxy-4,6-O-(phenylmethylene)-2-benzoate-α-D-allopyranoside 

Downstream Products

• 51969-94-9 (3aR)-4t-methoxy-2,8t-diphenyl-(3ar,5at,9ac,9bc)-octahydro-[1,3]dioxino[4',5':5,6]pyrano[4,3-d][1,3,2]oxazaborole 
• 99745-49-0 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-allopyranosid 
• 99679-82-0 ((2R,4aR,6S,7R,8S,8aS)-7-Hydroxy-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl)-carbamic acid methyl ester 
• 99679-92-2 Methyl-3-<(benzyloxycarbonyl)amino>-3,4-didesoxy-α-D-glycero-hex-3-enopyranosid-2-ulose 
• 99679-81-9 Methyl-4,6-O-benzyliden-3-desoxy-3-<(methoxycarbonyl)amino>-α-D-ribo-hexopyranosid-2-ulose 
• 99679-90-0 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-3-C-methyl-α-D-arabino-hexopyranosid-2-ulose 
• 99679-91-1 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-2-O-methyl-3-desoxy-α-D-erythro-hex-2-enopyranosid 
• 99679-78-4 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-arabino-hexopyranosid-2-ulose 
• 99679-80-8 Methyl-4,6-O-benzyliden-3-<(benzyloxycarbonyl)amino>-3-desoxy-α-D-ribo-hexopyranosid-2-ulose 

Relevant academic research and scientific papers

Enolates of Carbohydrates, 4. - Axial C-Alkylation in α-Position of α-Amino-α-deoxy-ketoses

Products of type 2a-c, 6, 10a, b, and 14a, b which are alkylated in α-position of the keto function are yielded by reaction of the α-amino-α-deoxy-uloses 1a-c, 5, 9a, and 13a, b with LDA, CH3I, HMPA in THF (method A) or KOtBu, CH3I in DMF (method B) in a