99683-12-2Relevant academic research and scientific papers
Reactions of α-or χ-Phenylthio Substituted Extended Enolate Anions Derived from Esters
Brownbridge, Peter,Durman, John,Hunt, Paul G.,Warren, Stuart
, p. 1947 - 1958 (2007/10/02)
The title anions are alkylated and acylated (α series only) exclusively at the α position.The α-phenylthio products give χ-phenylthio compounds by the PhS shift and the PhS group may be removed from the products in a number of ways.
ACYLATION OF EXTENDED ENOLATE IONS FROM α-PHENYLTHIO(PhS-)CROTONATE ESTERS
Durman, John,Warren, Stuart
, p. 2895 - 2898 (2007/10/02)
C-Acylation, like alkylation, occurs at the α-position of title compounds to give unsaturated keto-esters from which the PhS group may be removed.
