99686-75-6Relevant articles and documents
Stereoselection in the Michael Addition Reaction. 4. Diastereofacial Preferences in Lewis Acid Mediated Additions of Enolsilanes to Chiral Enones
Heathcock, Clayton H.,Uehling, David E.
, p. 279 - 280 (1986)
Chiral enones show good to excellent diastereofacial preference in their TiCl4-mediated reactions with achiral and chiral enolsilanes; the method is shown to be useful for the preparation of acyclic 1,5-diketones and 1,5-keto acids having two or three ste