Journal of Organic Chemistry p. 279 - 280 (1986)
Update date:2022-09-26
Topics:
Heathcock, Clayton H.
Uehling, David E.
Chiral enones show good to excellent diastereofacial preference in their TiCl4-mediated reactions with achiral and chiral enolsilanes; the method is shown to be useful for the preparation of acyclic 1,5-diketones and 1,5-keto acids having two or three ste
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