99701-64-1

Basic information

• Product Name: N-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)-methyl)-tetrahydro-2H-pyran-2-yl)-2,2,2-trichloroacetamide
• Synonyms: N-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)-methyl)-tetrahydro-2H-pyran-2-yl)-2,2,2-trichloroacetamide
• CAS NO: 99701-64-1
• Molecular Weight: 685.044
• Mol File: 99701-64-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: N-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)-methyl)-tetrahydro-2H-pyran-2-yl)-2,2,2-trichloroacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)-methyl)-tetrahydro-2H-pyran-2-yl)-2,2,2-trichloroacetamide(99701-64-1)
• EPA Substance Registry System: N-((2S,3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)-methyl)-tetrahydro-2H-pyran-2-yl)-2,2,2-trichloroacetamide(99701-64-1)

Safety Data

• Hazardous Substances Data: 99701-64-1(Hazardous Substances Data)

Upstream product

• 132201-75-3 2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate 
• 74808-09-6 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate 
• 848047-83-6 (S)-2-((benzyloxycarbonyl)amino)succinic acid 1-allyl ester 4-amide 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 90357-89-4 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl trichloroacetimidate 
• 594-65-0 trichloroacetamide 

Downstream Products

• 4132-27-8 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-β-D-glucopyranose 
• 85917-83-5 1-amino-2,3,4,6-tetra-O-benzyl-1-deoxy-α-D-glucopyranose 
• 1158857-87-4 C₄₄H₄₈N₄O₆ 
• 1158857-93-2 C₅₂H₅₄N₂O₇ 
• 1158857-90-9 C₃₈H₄₂N₂O₈ 
• 1063748-64-0 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-[(N'-2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)ureido]-α-D-glucopyranoside 

Relevant articles and documents

Organocatalytic direct α-selective N-glycosylation of amide with glycosyl trichloroacetimidate

Through the synergistic catalytic effect of the halogen bond (XB) donor and thiourea catalyst, a direct α-selective N-glycosylation of the amide residue of asparagine derivative was achieved using readily accessible glycosyl trichloroacetimidate. n-Butyl methyl ether was found to be the most suitable solvent for the α-selectivity.

Rearrangement of Benzylic Trichloroacetimidates to Benzylic Trichloroacetamides

The rearrangement of allylic trichloroacetimidates is a well-known transformation, but the corresponding rearrangement of benzylic trichloroacetimidates has not been explored as a method for the synthesis of benzylic amines. Conditions that provide the tr

Stereoselective rearrangement of trichloroacetimidates: application to the synthesis of α-glycosyl ureas

A new method for the stereoselective synthesis of r-glycosyl ureas, via nickel-catalyzed [1,3]-rearrangement of glycosyl trichloroacetimidates, has been developed. The r-stereoselectivity at the anomeric carbon of the resulting trichloroacetamides depends