99722-93-7Relevant academic research and scientific papers
Palladium-Catalyzed, Atmospheric Pressure Ethoxycarbonylation of Allylic Halides under the Influence of Sodium Ethoxide. A Facile Synthesis of β,γ-Unsaturated Esters
Kiji, Jitsuo,Okano, Tamon,Konishi, Hisatoshi,Nishiumi, Wataru
, p. 1873 - 1876 (2007/10/02)
Atmospheric pressure ethoxycarbonylation of allylic halides is realized under the influence of sodium ethoxide.This reaction is catalyzed by Na2PdCl4-bis(diphenylphosphino)ethane (dppe) and offers a convenient synthetic method to β,γ-unsaturated esters.
PALLADIUM(O)-CATALYZED CARBONYLATION OF ALLYL PHOSPHATES AND ALLYL ACETATES. SELECTIVE SYNTHESIS OF β,γ-UNSATURATED ESTERS.
Murahashi, Shun-Ichi,Imada, Yasushi,Taniguchi, Yuki,Higashiura, Shin-ya
, p. 4945 - 4948 (2007/10/02)
Palladium catalyzed carbonylations of allyl phosphates and allyl acetates give β,γ-unsaturated esters efficiently.The latter reaction requires bromide ion as a co-catalyst.
