99749-13-0Relevant academic research and scientific papers
AgF-mediated fluorinative homocoupling of gem -difluoroalkenes
Gao, Bing,Zhao, Yanchuan,Ni, Chuanfa,Hu, Jinbo
supporting information, p. 102 - 105 (2014/01/23)
A novel silver(I)-fluoride-mediated homocoupling reaction of β,β-difluorostyrene derivatives is described. The transformation is initiated via nucleophilic addition of silver(I) fluoride to β,β-difluorostyrenes, which is followed by dimerization of the corresponding benzylsilver intermediates. The reaction shows good substrate scope, functional group tolerance, and represents the first report on the reactivity of (α-trifluoromethyl)benzylsilver species.
Influence of Alkyl-Chain Fluorination on the Action of Mammary Tumor Inhibiting 2,3-Bis(hydroxyphenyl)butanes and 2,3-Bis(hydroxyphenyl)but-2-enes
Hartmann, Rolf W.,Heindl, Alexander,Schneider, Martin R.,Schoenenberger, Helmut
, p. 322 - 328 (2007/10/02)
trans-1,2-Bis(trifluoromethyl)-1,2-bis(4- and 3-hydroxyphenyl)ethenes 2 and 4 were prepared by reductive coupling (TiCl4/Zn/pyridine) of the methoxy-substituted α,α,α-trifluoroacetophenones, separation of the resulting cis- and trans-stilbene derivatives,
