99766-18-4

Upstream product

• 66270-36-8 2,2,2-trichloro-1,1-dimethylethoxychloroformate 
• 99766-11-7 17-(phenylthio)alloyohimb-16-ene 

Downstream Products

• 99766-13-9 <(2,2,2-trichloro-1,1-dimethylethoxy)carbonyl>-16-cyano-17-(phenylthio)alloyohimb-17-ene 
• 99783-13-8 16-cyano-17-(phenylthio)alloyohimb-17-ene 
• 99766-19-5 (4aS,13bS,14aS)-1-Bromo-2-phenylsulfanyl-1,4a,5,7,8,13b,14,14a-octahydro-4H-indolo[2',3':3,4]pyrido[1,2-b]isoquinoline-13-carboxylic acid 2,2,2-trichloro-1,1-dimethyl-ethyl ester 

Relevant academic research and scientific papers

Application of a Transition-Metal-Mediated Stereospecific Michael Reaction Equivalent to the Synthesis of Alloyohimbone

A stereospecific Michael reaction equivalent, based on a sulfur-substituted (?-allyl)palladium intermediate, has been applied as the key step in a synthesis of alloyohimbone (2).The use of the identical ?-allyl precursor in the absence of palladium provid