99796-91-5Relevant academic research and scientific papers
Hydrogen Transfer Reactions, 8. Heterogeneous Catalysis of Hydrogen Transfer by Metall Oxides
Heesing, Albert,Laue, Hans-Joachim
, p. 1232 - 1243 (2007/10/02)
For H-transfer of dihydroarenes in the condensed phase chromium(III) oxide proved to be a favorable catalyst.Hydrogen abstraction is a separate step occurring in a multistep ionic mechanism with moderate regio and stereo selectivity.The second step is the cis-hydrogenation of the acceptor.This reaction is accompanied by isomerisations (of alkenes and alkynes) and by H/D-scrambling.
