99897-70-8

Basic information

• Product Name: [Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]⁽¹⁺⁾*ClO₄^(1-)=[Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]ClO₄
• CAS NO: 99897-70-8
• Molecular Weight: 977.825
• Mol File: 99897-70-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]⁽¹⁺⁾*ClO₄^(1-)=[Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]ClO₄(CAS DataBase Reference)
• NIST Chemistry Reference: [Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]⁽¹⁺⁾*ClO₄^(1-)=[Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]ClO₄(99897-70-8)
• EPA Substance Registry System: [Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]⁽¹⁺⁾*ClO₄^(1-)=[Ru(ClC₆H₄CN)(P(C₆H₅)3)2(C₉H₇)]ClO₄(99897-70-8)

Safety Data

• Hazardous Substances Data: 99897-70-8(Hazardous Substances Data)

Upstream product

• 7791-07-3 sodium perchlorate monohydrate 
• 873-32-5 2-Chlorobenzonitrile 

Relevant articles and documents

INDENYL COMPLEXES OF RUTHENIUM(II). CRYSTAL STRUCTURE OF 5-C9H7)>ClO4.1/2CH2Cl2

The compound 5-C9H7)> (I) has been made in high yield by reaction of with indene and potassium hydroxide in ethanol and its reactions have been examined.Complex I reacts with appropriate nucleophiles to give the complexes 5-C9H7)> (X=H, CH3, I, SnCl3, C2Ph) and 5-C9H7)>.Heating of complex I with methanol in a sealed tube leads to the elimination of the indenyl group and decarbonylation of methanol.Cationic complexes of formulae 5-C9H7)>ClO4 (L=CH3CN, 2-ClC6H4CN, CH2=CHCN, 1,2-(CN)2C6H4, C2H4(CN)2, N2H4, CNBut, CO, C=CHPh, and C2H4) and 5-C9H7)>ClO4 (L-L=2,5-norbornadiene (nbd), tetrafluorobenzobarrelene (tfb), ethylenediamine (en), propylenediamine (pn), biimidazole (Hbim), 2,2'-bipyridine (bipy) and 1,10-phenanthroline (phen)) are obtained by treatment of complex I with the appropriate ligand and sodium perchlorate in methanol.Reaction of the vinylideneruthenium complex 1-C=CHPh)(PPh3)2(η5-C9H7)>ClO4 with oxygen gives 5-C9H7)>ClO4.The structure of 5-C9H7)>ClO4.1/2CH2Cl2 has been determined by X-ray diffraction.The space group is P with lattice constants a 18.5513(14), b 12.9165(5), and c 9.6898(5) Angstroem, and α 80.942(5), β 104.998(7) and γ 111.130(4) deg.Final R and Rw factors are 0.039 and 0.043, respectively, for the 6836 observed data (3?(I) criterion).The metal is bonded to an indenyl group through the five-membered ring, and hexacoordination of the ruthenium atom is completed by two triphenylphosphine ligands and a carbonyl group.