99922-75-5Relevant articles and documents
2,3-Rearrangement of 2-Aza- to 2,3-Diazabicycles in Redox Reactions of their N-Nitroso and N-Amino Derivatives
Heesing, Albert,Keller, Ludwig
, p. 1413 - 1423 (2007/10/02)
Reduction of 2-aza bicyclic nitrosamines (3a, 7), oxidation of N-amino derivatives (3b, 7a) and oxidative N-amination induces rearrangement by 2,3-shift and insertion of the exocyclic nitrogen (-> 4, 5, 8).This will only occur, when allyl-stabilised intermediates are formed by homolytic ring opening.It is favored by release of ring strain.