99930-76-4Relevant articles and documents
A NOVEL METHOD FOR THE PREPARATION OF SYMMETRICAL AND UNSYMMETRICAL ETHERS. TRITYL PERCHLORATE PROMOTED REDUCTION OF CARBONYL COMPOUNDS WITH TRIETHYLSILANE
Kato, Jun-ichi,Iwasawa, Nobuharu,Mukaiyama, Teruaki
, p. 743 - 746 (1985)
In the presence of a catalytic amount of trityl perchlorate, symmetrical ethers are prepared from aldehydes and triethylsilane, and unsymmetrical ethers are also obtained from carbonyl compounds, alkoxytrimethylsilanes and triethylsilane, in good yields, respectively.
Bismuth trichloride catalyzed efficient reductive etherification of carbonyl compounds with alcohols: A novel method for preparation of symmetrical and unsymmetrical ethers
Wada, Makoto,Nagayama, Sonoe,Mizutani, Kaori,Hiroi, Ryoichi,Miyoshi, Norikazu
, p. 248 - 249 (2007/10/03)
The reductive homocoupling of a carbonyl compound and heterocoupling of a carbonyl compound with a non-protected alcohol were both effected smoothly at room temperature with triethylsilane in the presence of a catalytic amount of bismuth trichloride to afford the corresponding ethers in good yields.