A NOVEL METHOD FOR THE PREPARATION OF SYMMETRICAL AND UNSYMMETRICAL ETHERS. TRITYL PERCHLORATE PROMOTED REDUCTION OF CARBONYL COMPOUNDS WITH TRIETHYLSILANE

DOI: 10.1246/cl.1985.743

Source and publish data:

Chemistry Letters p. 743 - 746 (1985)

Update date:2022-08-04

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Authors:

Kato, Jun-ichi

Iwasawa, Nobuharu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1985.743

In the presence of a catalytic amount of trityl perchlorate, symmetrical ethers are prepared from aldehydes and triethylsilane, and unsymmetrical ethers are also obtained from carbonyl compounds, alkoxytrimethylsilanes and triethylsilane, in good yields, respectively.

Full text of DOI:10.1246/cl.1985.743

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