99940-33-7Relevant academic research and scientific papers
Synthesis of 1,2-amino alcohols by decarboxylative coupling of amino acid derived α-amino radicals to carbonyl compounds: Via visible-light photocatalyst in water
Pan, Shulei,Jiang, Min,Hu, Jinjin,Xu, Ruigang,Zeng, Xiaofei,Zhong, Guofu
supporting information, p. 336 - 341 (2020/02/13)
A general and efficient visible-light photoredox-catalysed decarboxylative radical coupling reaction of N-aryl amino acids with aldehydes or ketones for the synthesis of various 1,2-amino alcohols by using water as the solvent at room temperature is described. This protocol is characterised by broad substrate scopes, mild reaction conditions and amenability to gram-scale synthesis, which opens up a simple, mild but effective method to produce 1,2-amino alcohols from readily available starting materials.
Green synthesis method of amino alcohol compounds under visible light catalysis
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Paragraph 0081; 0082, (2019/12/25)
The invention discloses a green synthesis method of amino alcohol compounds under visible light catalysis, and belongs to the technical field of organic synthesis. The green synthesis method specifically comprises the following steps that S1, 90.4mg of N-
Gold-catalyzed 1,2-difunctionalizations of aminoalkynes using only N- and O-containing oxidants
Mukherjee, Anupam,Dateer, Ramesh B.,Chaudhuri, Rupsha,Bhunia, Sabyasachi,Karad, Somnath Narayan,Liu, Rai-Shung
supporting information; experimental part, p. 15372 - 15375 (2011/11/07)
We report two viable routes for the 1,2-difunctionalization of aminoalkynes using only oxidants. In the presence of a gold catalyst, nitrones enable the oxoamination of aminoalkynes 1 to form 2-aminoamides 2. With a suitable gold catalyst, nitrosobenzenes implement an alkyne/nitroso metathesis of the same substrates to give 2-oxoiminylamides 3. These two novel oxidations also provide 1,2-aminoalcohols with opposite regioselectivity via NaBH4 reduction in situ.
Thiourea catalyzed aminolysis of epoxides under solvent free conditions. Electronic control of regioselective ring opening
Chimni, Swapandeep Singh,Bala, Neeraj,Dixit, Vaibhav A.,Bharatam, Prasad V.
experimental part, p. 3042 - 3049 (2010/06/14)
A reactant economizing process for the regioselective aminolysis of epoxides using equimolar quantities of reactants catalyzed by the double hydrogen bond donor N,N′-bis[3,5-bis(trifluoromethyl)phenyl]thiourea is reported. Regioselectivity of the reaction
