54731-27-0

Basic information

• Product Name: Silane, trimethyl[[1-(4-methylphenyl)ethenyl]oxy]-
• CAS NO: 54731-27-0
• Molecular Formula: C12H18OSi
• Molecular Weight: 206.36
• Mol File: 54731-27-0.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[1-(4-methylphenyl)ethenyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[1-(4-methylphenyl)ethenyl]oxy]-(54731-27-0)
• EPA Substance Registry System: Silane, trimethyl[[1-(4-methylphenyl)ethenyl]oxy]-(54731-27-0)

Safety Data

• Hazardous Substances Data: 54731-27-0(Hazardous Substances Data)

Upstream product

• 78279-92-2 2,3,5,6-tetramethyl-1,4-bis(trimethylsilyl)-1,4-diaza-2,5-cyclo-hexadiene 
• 619-41-0 4-(bromoacetyl)toluene 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 
• 122-00-9 para-methylacetophenone 
• 31469-15-5 1-methoxy-2-methyl-1-trimethylsiloxy-1-propene 
• 27607-77-8 trimethylsilyl trifluoromethanesulfonate 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 55991-68-9 5-(p-tolyl)-2,3-dihydro-2,3-furandione 
• 24437-49-8 2-(methylsulfonyl)-1-(p-tolyl)ethan-1-one 
• 61820-95-9 2-(toluene-4-sulfonyl)-1-p-tolylethanone 
• 75650-02-1 4-p-tolylnaphtho<2,3-d><1,3>dioxepin-6,11-dione 
• 75650-05-4 7-Methyl-9-p-tolyl-6,8-dioxa-cyclohepta[b]naphthalene-5,11-dione 
• 1150576-68-3 methyl 7-hydroxy-2-(4-methylphenyl)benzofuran-4-carboxylate 

Relevant articles and documents

β-Diazocarbonyl Compounds: Synthesis and their Rh(II)-Catalyzed 1,3 C?H Insertions

Herein, we describe the first electrophilic diazomethylation of ketone silyl enol ethers with diazomethyl-substituted hypervalent iodine reagents that gives access to unusual β-diazocarbonyl compounds. The potential of this unexplored class of diazo compounds for the development of new reactions was demonstrated by the discovery of a rare Rh-catalyzed intramolecular 1,3 C?H carbene insertion that led to complex cyclopropanes with excellent stereocontrol.

Lewis Acid-Catalyzed Carbofunctionalization of Uncommon C, N-Diacyliminium Ions: Controlling Regio- And Enantioselectivity

The tricyclic azepino[1,2-a]indole acetates 7, readily accessible by visible-light-driven catalytic photooxygenation of cyclohepta[b]indoles 1, are convenient precursors to novel and uncommon cyclic C,N-diacyliminium ions 3. We report here the first Lewis

Photoinduced Deaminative Alkylation for the Synthesis of γ-Ketoesters via Electron Donor–Acceptor Complex Formation

Visible-light-induced deaminative alkylation of Katritzky salts with silyl enol ethers has been developed. The reaction can proceed efficiently through electron donor–acceptor complex formation, avoiding the use of precious metal complexes or synthetically elaborate organic dyes. A series of functionalized γ-ketoesters was successfully obtained with good functional group tolerance and compatibility under mild and straightforward conditions.