99986-13-7Relevant academic research and scientific papers
Angular ligand constraint yields an improved olefin aziridination catalyst
Vedernikov, Andrei N.,Caulton, Kenneth G.
, p. 2591 - 2594 (2003)
(Matrix presented) The use of a pyridinophane, a macrocycle composed of three pyridines linked, via all ortho positions through CH2 or CH2CH2 groups, bound to copper, gives good performance (rate and yield) catalyzing the
A practical, fast, and high-yielding aziridination procedure using simple Cu(II) complexes containing N-donor pyridine-based ligands
Mohr, Fabian,Binfield, Seth A.,Fettinger, James C.,Vedernikov, Andrei N.
, p. 4833 - 4839 (2007/10/03)
Four-coordinate dichlorocopper(II) complexes derived from di(2-pyridyl)methanes or pyridine itself exhibit high catalytic activity in aziridination of regular olefins with PhINTs in weakly coordinating chloroform in the presence of 1-2 equiv of NaBAr
Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane- PhINTs systems
Vedernikov, Andrei N.,Caulton, Kenneth G.
, p. 162 - 163 (2007/10/03)
Mild catalytic dehydrogenation of cycloalkanes (cyclo-C5H 10, cyclo-C6H12, cyclo-C8H 16) and aziridination of resulting olefins is reported with PhINTs and copper-[2.1.1]-(2,6)-pyridinophane (L) complexes LCuXn (n = 1, 2; X = Cl, OTf) "activated" with NaBArF4 in dichloromethane solution.
