iodine monochloride basic information |
product name: |
iodine monochloride |
synonyms: |
iodinemonochlorideforsynthesis(5x25grams);iodinemonochloride,97%;iodinechloride,acs;iodine monochloride, reagent acs;iodine monochloride, acs;iodine monochloride solution (wijs' chloride);chloroiodide solution, iodine according to wijs for the iodine value determination, iodine monochloride solution, wijs solution;chloroiodide solution, wijs solution |
cas: |
7790-99-0 |
mf: |
cli |
mw: |
162.36 |
einecs: |
232-236-7 |
product categories: |
inorganics |
mol file: |
7790-99-0.mol |
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iodine monochloride chemical properties |
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iodine monochloride usage and synthesis |
chemical properties |
dark red or brown solid and/or liquid |
general description |
black crystals or a reddish brown oily liquid with a pungent odor. melting point 27°c (alpha form) or 14°c (beta form). corrosive to metals and tissue. |
air & water reactions |
reacts with air to form iodine pentaoxide (i2o5), which decomposes into iodine (i2) and oxygen (o2) with heat beginning at 275°c and proceeding rapidly at 350°c. soluble in water; reacts with water or steam to produce toxic and corrosive fumes [lewis]. |
reactivity profile |
iodine monochloride is moderately explosive when heated [lewis]. reacts with rubber and many organic materials. enflames (after a period of delay) with aluminum foil [mellor 2:119(1946-1947)]. reacts dangerously with other active metals. reacts vigorously with cadmium sulfide, lead sulfide, silver sulfide, and zinc sulfide [mellor 2, supp. 1:502(1956)]. combines very exothermically with phosphorus trichloride [mellor 2, supp. 1:502(1956)]. forms iodine pentaoxide in air which reacts explosively when warmed with carbon, sulfur, sugar, resin, or powdered combustible elements [mellor 8: 841(1946-1947)]. |
health hazard |
toxic; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. reaction with water or moist air will release toxic, corrosive or flammable gases. reaction with water may generate much heat that will increase the concentration of fumes in the air. fire will produce irritating, corrosive and/or toxic gases. runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. |
fire hazard |
non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. vapors may accumulate in confined areas (basement, tanks, hopper/tank cars etc.). substance will react with water (some violently), releasing corrosive and/or toxic gases and runoff. contact with metals may evolve flammable hydrogen gas. containers may explode when heated or if contaminated with water. |
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iodine monochloride preparation products and raw materials |
preparation products |
2,4-dichloro-5-iodopyrimidine-->3-cyano-4-hydroxybenzoic acid-->3-amino-2,4,6-triiodobenzoic acid-->2-amino-5-iodobenzoic acid-->6,10,12-trichloronaphth[2,3-c]acridine-5,8,14(13h)-trione-->n-acetyl-3,5-diiodo-l-tyrosine ethyl ester-->3,5-diiodosalicylic acid-->5-amino-2,4,6-triiodo-n-methylisophthalamic acid (50 mg)-->4-iodoanisole-->3-(3-amino-2,4,6-triiodophenyl)propionic acid-->5-iodoisatin-->2,6-diiodo-4-nitroaniline |
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