USD $1.00-10.00 / Kilogram
USD $1.00-10.00 / Kilogram
USD $1.00-1.00 / Kilogram
USD $1.00-10.00 / Kilogram
USD $1.00-10.00 / Kilogram
USD $1.00-10.00 / Kilogram
good quantity
titanium tetrachloride basic information |
product name: | titanium tetrachloride |
synonyms: | (t-4)-titaniumchloride(ticl4;tetrachlorure de titane;tetrachloruredetitane;tetrachloruredetitane(french);ticl4;titaantetrachloride;titane;titane(tetrachlorurede) |
cas: | 7550-45-0 |
mf: | cl4ti |
mw: | 189.68 |
einecs: | 231-441-9 |
product categories: | inorganic chemicals;tic14;inorganics;classes of metal compounds;ti (titanium) compounds;transition metal compounds;metal halide;catalysis and inorganic chemistry;lewis acids;titanium salts;alternative energy;catalysts;chemical synthesis;materials for hydrogen storage;materials science;metal and ceramic science;salts;synthetic reagents;titanium;ionic polymerization initiators;polymer science;polymerization initiators;reagents for polymerization;basic inorganic chemicals |
mol file: | 7550-45-0.mol |
titanium tetrachloride chemical properties |
mp | −25 °c(lit.) |
bp | 135-136 °c(lit.) |
density | 1.73 g/ml at 20 °c(lit.) |
vapor pressure | 50 mm hg ( 55 °c) |
refractive index | 1.61 |
fp | 46 °f |
storage temp. | flammables area |
solubility | h2o: soluble |
water solubility | reacts |
sensitive | moisture sensitive |
merck | 14,9478 |
stability: | stable. reacts with water. incompatible with moisture, ammonia, amines, alcohols, potassium and other chemically active metals. |
cas database reference | 7550-45-0(cas database reference) |
nist chemistry reference | titanium tetrachloride(7550-45-0) |
epa substance registry system | titanium chloride (ticl4) (t-4)-(7550-45-0) |
safety information |
hazard codes | c,f,xi,t |
risk statements | 36/37/38-67-65-63-48/20-34-14-11-23-40-37-48/23-39/23-20/21/22-36/38 |
safety statements | 26-7/8-62-46-45-36/37/39-24/25-23-16-60 |
ridadr | un 3289 6.1/pg 2 |
wgk germany | 2 |
rtecs | xr1925000 |
f | 21 |
tsca | yes |
hazardclass | 8 |
packinggroup | ii |
hazardous substances data | 7550-45-0(hazardous substances data) |
msds information |
provider | language |
---|---|
tetrachlorotitanium | english |
sigmaaldrich | english |
acros | english |
alfa | english |
titanium tetrachloride usage and synthesis |
chemical properties | colourless liquid with a penetrating odour |
usage | activates pyrrolidines for improved conversion, via a modified bouveault reaction, to the corresponding α,α-dimethylamines.1 |
general description | a colorless fuming liquid with a pungent odor. corrosive to metals and tissue. very toxic by inhalation. |
reactivity profile | titanium tetrachloride acts as an acid in aqueous solution. during the reduction of titanium tetrachloride to titanium metal with potassium, an explosion occurred. the system had been heated to 90°c [walter and mandell 1967]. addition directly to tetrahydrofuran caused a violent exothermic reaction [inorg. syn., 1982, 21, 135]. ethylene can polymerize at low pressure if catalyzed by titanium halides. (sundaram, k. m, m. m. shreehan, e. f. olszewski. thylene. kirk-othmer encyclopedia of chemical technology. john wiley & sons, inc. 2001.) |
health hazard | titanium tetrachloride is a highly corrosive, acute irritant to the skin, eyes, mucous membranes and the respiratory tract. it is capable of causing death or permanent injury due to exposures encountered in normal use. even short contact may lead to eye inflammation which may result in corneal opacities. |
fire hazard | material will react with water to produce hydrochloric acid. titanium tetrachloride may ignite other combustible materials (e.g., wood, oil, etc.). flammable, poisonous gases may accumulate in tanks and hopper cars. runoff to sewer may create fire or explosion hazard. reacts strongly with water to release hydrochloric acid and heat. avoid water, moist air. stable in concentrated aqueous solutions. avoid contact with moisture; the chemical absorbs moisture from air and evolves dense white fumes. |
titanium tetrachloride preparation products and raw materials |