USD $6.00-9.00 / Gram
USD $6.00-9.00 / Gram
USD $14.60-15.00 / Metric Ton
USD $6.00-9.00 / Gram
USD $20.00-35.00 / Metric Ton
USD $4.50-5.00 / Liter
USD $100.00-150.00 / Kilogram
USD $4.50-5.00 / Liter
USD $6.00-9.00 / Gram
product name: | butyl isocyanate |
synonyms: | 1-isocyanato-butan;bic;butane,1-isocyanato-;n-bic;n-butylisocyanate(asimpurity);n-c4h9nco;akos bbs-00004256;1-butyl isocyanate |
cas: | 111-36-4 |
mf: | c5h9no |
mw: | 99.13 |
einecs: | 203-862-8 |
product categories: | pharmaceutical intermediates;isocyanate;organics;isocyanates;nitrogen compounds;organic building blocks;building blocks;chemical synthesis;nitrogen compounds;organic building blocks |
mol file: | 111-36-4.mol |
butyl isocyanate chemical properties |
mp | 85.5℃ |
bp | 115 °c(lit.) |
density | 0.88 g/ml at 25 °c(lit.) |
vapor density | 3 (vs air) |
vapor pressure | 10.6 mm hg ( 20 °c) |
refractive index |
n |
fp | 64 °f |
storage temp. | 2-8°c |
merck | 13,1574 |
cas database reference | 111-36-4(cas database reference) |
nist chemistry reference | butane, 1-isocyanato-(111-36-4) |
epa substance registry system | butane, 1-isocyanato-(111-36-4) |
safety information |
hazard codes | f,t+ |
risk statements | 11-21/22-26-34-37-42/43 |
safety statements | 23-26-28-36/37/39-45 |
ridadr | un 2485 6.1/pg 1 |
wgk germany | 1 |
rtecs | nq8250000 |
f | 10-19-21 |
hazardclass | 6.1(a) |
packinggroup | i |
hazardous substances data | 111-36-4(hazardous substances data) |
chemical properties | colorless to faintly yellow liquid |
general description | a clear, colorless liquid with a pungent odor. flash point 68°f. very toxic by ingestion, and may also be toxic by skin absorption and inhalation. vapors heavier than air. less dense than water and insoluble in water. produces toxic oxides of nitrogen during combustion. |
air & water reactions | highly flammable. extremely slow decomposition by water. less dense than water and insoluble in water. |
reactivity profile | isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to release toxic gases. reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. acids and bases initiate polymerization reactions in these materials. some isocyanates react with water to form amines and liberate carbon dioxide. base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. such reactions in the absence of solvents often occur with explosive violence [wischmeyer 1969]. |
health hazard | toxic; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. bromoacetates and chloroacetates are extremely irritating/lachrymators. reaction with water or moist air will release toxic, corrosive or flammable gases. reaction with water may generate much heat that will increase the concentration of fumes in the air. fire will produce irritating, corrosive and/or toxic gases. runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. |
fire hazard | highly flammable: will be easily ignited by heat, sparks or flames. vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. most vapors are heavier than air. they will spread along ground and collect in low or confined areas (sewers, basements, tanks). vapors may travel to source of ignition and flash back. substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. contact with metals may evolve flammable hydrogen gas. containers may explode when heated or if contaminated with water. |
butyl isocyanate preparation products and raw materials |