149430-73-9Relevant articles and documents
Synthesis method of compound with biphenyl dimer structure
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, (2020/07/24)
The invention provides a synthesis method of a compound with a biphenyl dimer structure as shown in a formula A which is described in the specification. According to the synthesis method, 1,5-dibromo-pentane and 4-bromobenzaldehyde are used as raw materials, and the compound shown in the formula A is prepared through the steps of Grignard reaction, coupling and the like. The method is low in raw material price, high in yield, convenient to purify and suitable for industrial production.
Method for preparing dimer containing benzonitrile terminal
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Paragraph 0039; 0047; 0048; 0049; 0050, (2017/06/02)
The invention provides a method for preparing dimer containing a benzonitrile terminal. The method comprises the following steps: reacting a compound shown in the formula 1 and an organic solvent under the protection of nitrogen at a controlled temperature with added Lewis acid, adding a compound shown in the formula 2 while performing stirring, and performing heating reflux to obtain a compound shown in the formula 3; mixing the compound shown in the formula 3 with a strong acid solvent, controlling the temperature and adding a triethyl silicane solvent dropwise while performing stirring, and carrying out stirring and heating reflux to obtain a compound shown in the formula 4; and reacting the compound shown in the formula 4 with a compound shown in the formula 5 in the function of an alkaline compound, a catalyst, hydrazine hydrate, tetrahydrofuran and water, performing stirring while carrying out nitrogen replacement, and performing heating reflux to obtain the compound shown in the formula M. Compared with other methods, the method for preparing dimer containing a benzonitrile terminal is available in raw materials, simple in step, and high in yield, is suitable for massive industrial production, and is beneficial for application of a display liquid crystal material.