1542796-14-4 Usage
Molecular structure
Consists of a pyridine ring, a tert-butyl group, an anthracen-9-yl moiety, and a dihydrobenzo[d][1,3]oxaphosphol-2-yl group.
Pyridine ring
A heterocyclic aromatic organic compound with the formula C5H5N, similar to benzene but with one CH group replaced by nitrogen.
Tert-butyl group
A saturated hydrocarbon group with the formula C(CH3)3, which provides steric hindrance and stability to the molecule.
Anthracen-9-yl moiety
A part of the molecule derived from anthracene, a polycyclic aromatic hydrocarbon with the formula C14H10, known for its optical and electronic properties.
Dihydrobenzo[d][1,3]oxaphosphol-2-yl group
A phosphine oxide derivative with a five-membered benzene ring fused to a three-membered oxaphosphole ring, contributing to the compound's unique properties.
Potential applications
The compound may be useful in various applications, such as organic chemistry as a reagent or catalyst, due to its unique structure and properties.
Scientific research
The compound's structure suggests that it may have interesting and valuable properties for further study in scientific research.
Industrial applications
The compound's potential use in scientific research may lead to the development of new industrial applications, taking advantage of its unique properties and reactivity.
Check Digit Verification of cas no
The CAS Registry Mumber 1542796-14-4 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,5,4,2,7,9 and 6 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1542796-14:
(9*1)+(8*5)+(7*4)+(6*2)+(5*7)+(4*9)+(3*6)+(2*1)+(1*4)=184
184 % 10 = 4
So 1542796-14-4 is a valid CAS Registry Number.
1542796-14-4Relevant articles and documents
NOVEL CHIRAL NITROGEN-PHOSPHORUS LIGANDS AND THEIR USE FOR ASYMMETRIC HYDROGENATION OF ALKENES
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Page/Page column 24; 25; 26, (2015/02/02)
The invention relates to a series of novel chiral nitrogen-phosphorus ligands of formulae (Ia) and (Ib): wherein R1-R3 and X are as defined herein. The invention also relates to chiral metal complexes prepared with these chiral nitrogen-phosphorus ligands. The chiral metal complexes are useful as catalysts for carrying out asymmetric hydrogenation.
Synthesis of pyridyl-dihydrobenzooxaphosphole ligands and their application in asymmetric hydrogenation of unfunctionalized alkenes
Qu, Bo,Samankumara, Lalith P.,Savoie, Jolaine,Fandrick, Daniel R.,Haddad, Nizar,Wei, Xudong,Ma, Shengli,Lee, Heewon,Rodriguez, Sonia,Busacca, Carl A.,Yee, Nathan K.,Song, Jinhua J.,Senanayake, Chris H.
, p. 993 - 1000 (2014/03/21)
Synthesis of the electron-rich 2-substituted-6-(phenylsulfonyl)pyridines is presented. A series of air-stable, tunable, P-chiral pyridyl- dihydrobenzooxaphosphole ligands were designed and synthesized by a diastereoselective SNAr substitution of the corresponding sulfonyl pyridines. The ligands were successfully applied in the Ir-catalyzed asymmetric hydrogenation of unfunctionalized alkenes with good enantioselectivities.
