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N,N-Dimethylformamide (68-12-2) 's Synthetic route

Dimethylamine
124-40-3

Dimethylamine

Chloroform
67-66-3

Chloroform

N,N-Dimethylformamide
68-12-2

N,N-Dimethylformamide

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Combustion and sublimation calorimetric studies on acetylurea and trimethyl isocyanurate

Imamura, Akira  Murata, Shigeo  Sakiyama, Minoru

Standard enthalpies of formation in the crystalline and gaseous states have been determined for acetylurea and trimethyl isocyanurate by oxygen bomb-combustion calorimetry and sublimation calorimetry.Derived values are as follows:

.Stabilization energies related to intramolecular interaction between ?-electrons of carbonyl groups and lone-pair electrons of adjacent nitrogen atoms have been evaluated for acetamide and urea as well as for these compounds as enthalpy changes of "isodesmic" reactions using ethane as a reagent for the cleavage of CO-N bonds and are discussed.

Thermal decomposition of trimethylamine borane as a precursor to nanocrystalline CVD BC x N y films

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We have studied the kinetics of BC x N y chemical vapor deposition through trimethylamine borane decomposition at atmospheric pressure. The rate constant of the heterogeneous interaction between trimethylamine borane and an adsorption center has been determined to be k s 0 = 2.7 × 107exp(-10560/T) cm/s. The obtained kinetic parameters of the reaction fully determine the growth rate of nanocrystalline carbonitride films under kinetic control. The film thickness has been determined as a function of time, temperature, reactant concentration, and reactor dimensions.

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